[OPEN ACCESS] Tuning the structure and habit of iron oxide mesocrystals

Erik Wetterskog*, Alice Klapper, Sabrina Disch, Elisabeth Josten, Raphaël P. Hermann, Ulrich Rücker, Thomas Brückel, Lennart Bergström and German Salazar-Alvarez*

Nanoscale (2016)
DOI: 10.1039/C6NR03776C


Abstract:
A precise control over the meso- and microstructure of ordered and aligned nanoparticle assemblies, i.e., mesocrystals, is essential in the quest of exploiting collective material properties for potential applications. In this work, we produce evaporation-induced self-assembled mesocrystals with different mesostructures and crystal habits based on iron oxide nanocubes by varying the nanocube size and shape, and by applying magnetic fields. A full 3D characterization of the mesocrystals was performed using image analysis, high-resolution scanning electron microscopy and Grazing Incidence Small Angle X-ray Scattering (GISAXS). This enabled structural determination of e.g. multi-domain mesocrystals with complex crystal habits, and the quantification of interparticle distances with sub-nm precision. Mesocrystals of small nanocubes (l = 8.6 – 12.6 nm) are isostructural with a body centred tetragonal (bct) lattice whereas assembly of the largest nanocubes in this study (l = 13.6 nm) additionally form a simple cubic (sc) lattice. The mesocrystal habit can be tuned from a square, hexagonal to star-like and pillar shapes depending on the particle size, shape, and the strength of the applied magnetic field. Finally, we outline a qualitative phase diagram of the evaporation-induced self-assembled superparamagnetic iron oxide nanocube mesocrystals based on nanocube edge length and magnetic field strength.